Summary

General Principles

The Schrödinger Equation

d2ψdx2=−2mℏ2[E−U(x)]ψ(x)

This equation determines the wave function ψ(x) and, through ψ(x), the probabilities of finding a particle of mass m with potential energy U(x).

Solving Quantum-Mechanics Problems

Model Determine an appropriate potential-energy function U(x).

Visualize Draw the potential-energy curve.

  • Establish boundary conditions.

Solve Draw graphs of ψ(x) and |ψ(x)|2.

  • Determine the allowed energy levels.

  • Calculate probabilities, wavelengths, and other quantities.

Review Does the result have correct units and answer the question?

Boundary conditions

  • ψ(x) is a continuous function.

  • ψ(x)→0 as x→±∞.

  • ψ(x)=0 in a region where it is physically impossible for the particle to be.

  • ψ(x) is normalized.

Shapes of wave functions

  • The wave function oscillates in the region between the classical turning points.

  • State n has n antinodes.

  • Node spacing and amplitude increase as kinetic energy K decreases.

  • ψ(x) decays exponentially in a classically forbidden region.

The figure illustrates the potential energy diagram depicted by a graph of U of x versus x.

Quantum-mechanical models are characterized by the particle’s potential-energy function U(x).

  • Wave-function solutions exist for only certain values of E. Thus energy is quantized.

  • Photons are emitted or absorbed in quantum jumps.

The figure illustrates the energy level diagram with an energy barrier.

Important Concepts

Quantum-mechanical tunneling

A wave function can penetrate into a classically forbidden region with

ψ(x)=ψedgee−(x−L)/η

where the penetration distance is

η=ℏ2m(U0−E)

The probability of tunneling through a barrier of width w is

Ptunnel=e−2w/η
 The figure illustrates a wave function entering a classically forbidden region in a potential energy diagram.
 The figure illustrates tunneling through a barrier depicted by an energy potential diagram.

The correspondence principle says that the quantum world blends smoothly into the classical world for high quantum numbers. This is seen by comparing |ψ(x)|2 to the classical probability density

Pclass=2Tv(x)

Pclass expresses the idea that a classi-cal particle is more likely to be found where it is moving slowly.

Applications

Particle in a rigid box: En=n2h28mL2     n=1, 2, 3,…

Quantum harmonic oscillator: En=(n−12) ℏω   n=1, 2, 3,…

Other applications were studied through numerical solution of the Schrödinger equation.

Terms and Notation