This equation determines the wave function and, through , the probabilities of finding a particle of mass with potential energy .
Model Determine an appropriate potential-energy function .
Visualize Draw the potential-energy curve.
Establish boundary conditions.
Solve Draw graphs of and .
Determine the allowed energy levels.
Calculate probabilities, wavelengths, and other quantities.
Review Does the result have correct units and answer the question?
is a continuous function.
as .
in a region where it is physically impossible for the particle to be.
is normalized.
The wave function oscillates in the region between the classical turning points.
State has antinodes.
Node spacing and amplitude increase as kinetic energy decreases.
decays exponentially in a classically forbidden region.
Quantum-mechanical models are characterized by the particle’s potential-energy function .
Wave-function solutions exist for only certain values of . Thus energy is quantized.
Photons are emitted or absorbed in quantum jumps.
A wave function can penetrate into a classically forbidden region with
where the penetration distance is
The probability of tunneling through a barrier of width is
The correspondence principle says that the quantum world blends smoothly into the classical world for high quantum numbers. This is seen by comparing to the classical probability density
expresses the idea that a classi-cal particle is more likely to be found where it is moving slowly.
Particle in a rigid box:
Quantum harmonic oscillator:
Other applications were studied through numerical solution of the Schrödinger equation.