Our problem-solving strategy for classical mechanics focused on identifying and using forces. In quantum mechanics we’re interested in energy rather than forces. The critical step in solving a problem in quantum mechanics is to determine the particle’s potential-energy function . Identifying the interactions that cause a potential energy is the physics of the problem. Once the potential-energy function is known, it is “just mathematics” to solve for the wave function.
MODEL Determine a potential-energy function that describes the particle’s interactions. Make simplifying assumptions.
VISUALIZE The potential-energy curve is the pictorial representation.
Draw the potential-energy curve.
Identify known information.
Establish the boundary conditions that the wave function must satisfy.
SOLVE The Schrödinger equation is the mathematical representation.
Utilize the boundary conditions.
Normalize the wave functions.
Draw graphs of and .
Determine the allowed energy levels.
Calculate probabilities, wavelengths, or other specific quantities.
REVIEW Check that your result has the correct units, is reasonable, and answers the question.
The solutions to the Schrödinger equation are the stationary states of the system. Bohr had postulated the existence of stationary states, but he didn’t know how to find them. Now we have a strategy for finding them.
Bohr’s idea of transitions, or quantum jumps, between stationary states remains very important in Schrödinger’s quantum mechanics. The system can jump from one stationary state, characterized by wave function and energy , to another state, characterized by and , by emitting or absorbing a photon of frequency
Thus the solutions to the Schrödinger equation will allow us to predict the emission and absorption spectra of a quantum system. These predictions will test the validity of Schrödinger’s theory.