38.1.3 The Stopping Potential

Photoelectrons leave the cathode with kinetic energy. An electron with energy Eelec inside the metal loses energy ΔE as it escapes, so it emerges as a photoelectron with K=Eelec−ΔE. The work function energy E0 is the minimum energy needed to remove an electron, so the maximum possible kinetic energy of a photoelectron is

Kmax=Eelec−E0 (38.1)

Some photoelectrons reach the anode, creating a measurable current, but many do not. However, as FIGURE 38.5 shows:

FIGURE 38.5 The photoelectron current depends on the anode potential.

The figure consists of three parts that illustrate the dependence of photoelectric current on anode potential.
FIGURE 38.5 Full Alternative Text

Let the cathode be the point of zero potential energy, as shown in FIGURE 38.6. An electron emitted from the cathode with kinetic energy Ki has initial total energy

Ei=Ki+Ui=Ki+0=Ki

When the electron reaches the anode, which is at potential ΔV relative to the cathode, it has potential energy U=q ΔV=−e ΔV and final total energy

Ef=Kf+Uf=Kf−e ΔV

From conservation of energy, Ef=Ei, the electron’s final kinetic energy is

Kf=Ki+e ΔV (38.2)

The electron speeds up (Kf>Ki) if ΔV is positive. The electron slows down if ΔV is negative, but it still reaches the anode (Kf>0) if Ki is large enough.

FIGURE 38.6 Energy is conserved.

The figure illustrates the conservation of energy through an experimental setup.
FIGURE 38.6 Full Alternative Text

An electron with initial kinetic energy Ki will stop just as it reaches the anode if the potential difference is ΔV=−Ki/e. The potential difference that turns back the very fastest electrons, those with K=Kmax, and thus stops the current is

ΔVstop fastest electrons=−Kmaxe

By definition, the potential difference that causes the electron current to cease is ΔV=−Vstop, where Vstop is the stopping potential. The stopping potential is

Vstop=Kmaxe (38.3)

Thus the stopping potential tells us the maximum kinetic energy of the photoelectrons.

EXAMPLE 38.1 The classical photoelectric effect

A photoelectric-effect experiment is performed with an aluminum cathode. An electron inside the cathode has a speed of 1.5×106 m/s. If the potential difference between the anode and cathode is −2.00 V, what is the highest possible speed with which this electron could reach the anode?

MODEL Energy is conserved.

SOLVE If the electron escapes with the maximum possible kinetic energy, its kinetic energy at the anode will be given by Equation 38.2 with ΔV=−2.00 V. The electron’s initial kinetic energy is

Eelec=12mv2=12(9.11×10−31 kg)(1.5×106 m/s)2=1.025×10−18 J=6.41 eV

Its maximum possible kinetic energy as it leaves the cathode is

Ki=Kmax=Eelec−E0=2.13 eV

where E0=4.28 eV is the work function of aluminum. Thus the kinetic energy at the anode, given by Equation 38.2, is

Kf=Ki+e ΔV=2.13 eV−(e)(2.00 V)=0.13 eV

Notice that the electron loses 2.00 eV of kinetic energy as it moves through the potential difference of −2.00 V, so we can compute the final kinetic energy in eV without having to convert to joules. However, we do need joules to find the final speed:

Kf=12mvf2=0.13 eV=2.1×10−20 J vf=2Kfm=2.1×105 m/s