Chapter 38 Quantization

A photograph of the individual atoms in a silicon wafer seen using a scanning tunneling microscope.

Individual atoms are seen in this scanning tunneling microscope image of the surface of a silicon wafer.

In This Chapter, you will learn about the quantization of energy for light and matter.

What is quantization?

Quantization is the process of changing a continuous variable into a variable that has only discrete values. Energy, in classical physics, can have any value. But things are different at the atomic level.

  • The energy of a light wave is divided into discrete “chunks,” or quanta, called photons.

  • The electrons of an atom can exist only in certain states with discrete energies. These are the quantum states of the atom.

What are photons?

The photon model of light says that light consists of particle-like units called photons.

  • The energy of a photon of frequency f is quantized: Ephoton=hf, where h is Planck’s constant.

  • At very low intensity, light is detected as discrete particle-like events.

《 LOOKING BACK Section 33.2 Interference

The figure illustrates photon interference.

What are the consequences of photons?

  • Photons explain the photoelectric effect, where short-wavelength light ejects electrons from a metal surface but long-wavelength light does not.

  • Photons also explain Compton scattering, where the wavelength of x rays is shifted when the x rays scatter from a target.

    The figure illustrates the photoelectric effect.

What are matter waves?

You’ll learn that particles of matter, such as electrons and neutrons, have wave-like properties and can even undergo interference. The de Broglie wavelength of a particle of mass m and speed v is λ=h/mv, where, again, h is Planck’s constant.

The figure illustrates electron interference.

What are the consequences of matter waves?

  • A wave-like particle confined to a box sets up standing waves as it reflects back and forth. You’ll see that this leads to quantized energy levels.

  • The quantum theory of matter, beginning with Bohr and continuing with quantum mechanics (see Chapter 40) is based on matter’s wave-like properties.

    The figure illustrates the stationary waves formed by a particle in a box.

What is the Bohr model of the atom?

The Bohr model adds quantum ideas to Rutherford’s solar-system atom.

  • Electrons can orbit with only certain discrete radii and energies.

  • Photons are emitted and absorbed when electrons jump between energy levels.

《 LOOKING BACK Section 37.6 Rutherford’s model

The figure illustrates an energy level diagram.

Learning Objectives

After studying this chapter, you should be able to

  1. 38.1 Calculate the threshold wavelength and stopping potential for the photoelectric effect.

  2. 38.2 Apply the photon model of light.

  3. 38.3 Calculate the de Broglie wavelengths of particles with mass.

  4. 38.4 Solve problems about the energy levels of a particle in a box.

  5. 38.5 Solve problems about energy levels and quantum jumps.

  6. 38.6 Work with the Bohr model of the hydrogen atom.

  7. 38.7 Calculate the spectrum of hydrogen and hydrogen-like ions.