27.4.1 Superconductivity

In 1911, the Dutch physicist Heike Kamerlingh Onnes was studying the conductivity of metals at very low temperatures. Scientists had just recently discovered how to liquefy helium, and this opened a whole new field of low-temperature physics. As we noted above, metals become better conductors (i.e., they have higher conductivity and lower resistivity) at lower temperatures. But the effect is gradual. Onnes, however, found that mercury suddenly and dramatically loses all resistance to current when cooled below a temperature of 4.2 K. This complete loss of resistance at low temperatures is called superconductivity.

Later experiments established that the resistivity of a superconducting metal is not just small, it is truly zero. The electrons are moving in a frictionless environment, and charge will continue to move through a superconductor without an electric field. Superconductivity was not understood until the 1950s, when it was explained as being a specific quantum effect.

Superconducting wires can carry enormous currents because the wires are not heated by electrons colliding with the atoms. Very strong magnetic fields can be created with superconducting electromagnets, but applications remained limited for many decades because all known superconductors required temperatures less than 20 K. This situation changed dramatically in 1986 with the discovery of high-temperature superconductors. These ceramic-like materials are superconductors at temperatures as “high” as 125 K. Although −150°C may not seem like a high temperature to you, the technology for producing such temperatures is simple and inexpensive. Thus many new superconductor applications are likely to appear in coming years.

A photograph of a small magnet that levitates above a disk.

Superconductors have unusual magnetic properties. Here a small permanent magnet levitates above a disk of the high-temperature superconductor YBa2Cu3O7 that has been cooled to liquid-nitrogen temperature.