Chapter 18 A Macroscopic Description of Matter

A photograph of lava flowing over a rocky terrain.

The phrase “solid as a rock” is cast in doubt when rocks melt, as they do in this flowing lava.

In This Chapter, you will learn some of the characteristics of macroscopic systems.

What are the phases of matter?

Most materials can exist as a solid, a liquid, or a gas. These are the most common phases of matter.

The figure consists of three circles labeled Solid, Liquid, and Gas placed side by side.

Starting with this chapter and continuing through Part V you will come to understand that the macroscopic properties of matter, such as volume, density, pressure, and temperature, can often be understood in terms of the microscopic motions of their atoms and molecules. This micro/macro connection is an important part of our modern understanding of matter.

《 LOOKING BACK Sections 14.1, 14.2, and 14.3 Fluids and pressure

What is temperature?

You’re familiar with temperature, but what does it actually measure? We’ll start with the simple idea that temperature measures “hotness” and “coldness,” but we’ll come to recognize that temperature measures a system’s thermal energy. We’ll study the well-known fact that objects expand or contract when the temperature changes.

The figure consists of two boxes labeled Before and After that consists of boxes attached to a vertically oriented thermometer at the left on the upper right corner.

What is an ideal gas?

We’ll model a gas as consisting of tiny, hard spheres that occasionally collide but otherwise do not interact with each other. This ideal gas obeys a law relating four state variables—the ideal-gas law:

pV=nRT

You will use the ideal-gas law to analyze what happens when a gas changes state.

The figure illustrates a squared box with a pressure gauge labeled p at the top of the box.

What is an ideal-gas process?

Heating or compressing a gas is a process that changes the state of the gas. An ideal-gas process can be shown as a trajectory through a pV diagram. We’ll study three basic processes:

  • Constant-volume process

  • Constant-pressure process

  • Constant-temperature process

The figure illustrates a pressure versus volume graph.

Why are macroscopic properties important?

Physicists, chemists, biologists, and engineers all work with matter at the macroscopic level. Everything from basic science to engineering design depends on knowing how materials respond when they are heated, compressed, melted, or otherwise changed by factors in their environment. Changing states of matter underlie devices ranging from car engines to power plants to spacecraft.

Learning Objectives

After studying this chapter, you should be able to

  1. 18.1 Recognize the basic characteristics of solids, liquids, and gases.

  2. 18.2 Work with moles and atomic masses.

  3. 18.3 Work with different temperature scales.

  4. 18.4 Calculate the thermal expansion of solids and liquids.

  5. 18.5 Read and interpret a phase diagram.

  6. 18.6 Solve problems about ideal gases.

  7. 18.7 Identify and work with isochoric, isobaric, and isothermal ideal-gas processes.