17.6.1 Application: Thin-Film Optical Coatings

The shimmering colors of soap bubbles and oil slicks, as seen in the photo at the beginning of the chapter, are due to the interference of light waves. In fact, the idea of light-wave interference in one dimension has an important application in the optics industry, namely the use of thin-film optical coatings. These films, less than 1 μm (10−6 m) thick, are placed on glass surfaces, such as lenses, to control reflections from the glass. Antireflection coatings on the lenses in cameras, microscopes, and other optical equipment are examples of thin-film coatings.

FIGURE 17.23 shows a light wave of wavelength λ approaching a piece of glass that has been coated with a transparent film of thickness d whose index of refraction is n. The air-film boundary is a discontinuity at which the wave speed suddenly decreases, and you saw earlier, in Figure 17.7, that a discontinuity causes a reflection. Most of the light is transmitted into the film, but a little bit is reflected.

FIGURE 17.23 The two reflections, one from the coating and one from the glass, interfere.

The figure illustrates interference between two reflections from a glass and its coating respectively.
FIGURE 17.23 Full Alternative Text

Furthermore, you saw in Figure 17.7 that the wave reflected from a discontinuity at which the speed decreases is inverted with respect to the incident wave. For a sinusoidal wave, which we’re now assuming, the inversion is represented mathematically as a phase shift of π rad. The speed of a light wave decreases when it enters a material with a larger index of refraction. Thus a light wave that reflects from a boundary at which the index of refraction increases has a phase shift of π rad. There is no phase shift for the reflection from a boundary at which the index of refraction decreases. The reflection in Figure 17.23 is from a boundary between air (nair=1.00) and a transparent film with nfilm>nair, so the reflected wave is inverted due to the phase shift of π rad.

When the transmitted wave reaches the glass, most of it continues on into the glass but a portion is reflected back to the left. We’ll assume that the index of refraction of the glass is larger than that of the film, nglass>nfilm, so this reflection also has a phase shift of π rad. This second reflection, after traveling back through the film, passes back into the air. There are now two equal-frequency reflected waves traveling to the left, and these waves will interfere. If the two reflected waves are in phase, they will interfere constructively to cause a strong reflection. If the two reflected waves are out of phase, they will interfere destructively to cause a weak reflection or, if their amplitudes are equal, no reflection at all.

This suggests practical uses for thin-film optical coatings. The reflections from glass surfaces, even if weak, are often undesirable. For example, reflections degrade the performance of optical equipment. These reflections can be eliminated by coating the glass with a film whose thickness is chosen to cause destructive interference of the two reflected waves. This is an antireflection coating.

The amplitude of the reflected light depends on the phase difference between the two reflected waves. This phase difference is

Δϕ=ϕ2−ϕ1=(kx2+ϕ20+π rad)−(kx1+ϕ10+π rad)        =2πΔxλf+Δϕ0 (17.30)

where we explicitly included the reflection phase shift of each wave. In this case, because both waves had a phase shift of π rad, the reflection phase shifts cancel.

The wavelength λf is the wavelength in the film because that’s where the path-length difference Δx occurs. You learned in Chapter 16 that the wavelength in a transparent material with index of refraction n is λf=λ/n, where the unsubscripted λ is the wavelength in vacuum or air. That is, λ is the wavelength that we measure on “our” side of the air-film boundary.

A photograph of two reading glasses.

Antireflection coatings use the interference of light waves to nearly eliminate reflections from glass surfaces.

The path-length difference between the two waves is Δx=2d because wave 2 travels through the film twice before rejoining wave 1. The two waves have a common origin—the initial division of the incident wave at the front surface of the film—so the inherent phase difference is Δϕ0=0. Thus the phase difference of the two reflected waves is

Δϕ=2π2dλ/n=2π2ndλ (17.31)

The interference is constructive, causing a strong reflection, when Δϕ=m⋅2π rad. So when both reflected waves have a phase shift of π rad, constructive interference occurs for wavelengths

λC=2ndm  m=1, 2, 3,…  (constructive interference) (17.32)

You will notice that m starts with 1, rather than 0, in order to give meaningful results. Destructive interference, with minimum reflection, requires Δϕ=(m−12)⋅2π rad. This—again, when both waves have a phase shift of π rad—occurs for wavelengths

λD=2ndm−12  m=1, 2, 3,…  (destructive interference) (17.33)

We’ve used m−12, rather than m+12, so that m can start with 1 to match the condition for constructive interference.

NOTE   The exact condition for constructive or destructive interference is satisfied for only a few discrete wavelengths λ. Nonetheless, reflections are strongly enhanced (nearly constructive interference) for a range of wavelengths near λC. Likewise, there is a range of wavelengths near λD for which the reflection is nearly canceled.

EXAMPLE 17.9 Designing an antireflection coating

Magnesium fluoride (MgF2) is used as an antireflection coating on lenses. The index of refraction of MgF2 is 1.39. What is the thinnest film of MgF2 that works as an antireflection coating at λ=510 nm, near the center of the visible spectrum?

MODEL Reflection is minimized if the two reflected waves interfere destructively.

SOLVE The film thicknesses that cause destructive interference at wavelength λ are

d=(m−12)λ2n

The thinnest film has m=1. Its thickness is

d=λ4n=510 nm4(1.39)=92 nm

The film thickness is significantly less than the wavelength of visible light!

REVIEW The reflected light is completely eliminated (perfect destructive interference) only if the two reflected waves have equal amplitudes. In practice, they don’t. Nonetheless, the reflection is reduced from ≈ 4% of the incident intensity for “bare glass” to well under 1%. Furthermore, the intensity of reflected light is much reduced across most of the visible spectrum (400–700 nm), even though the phase difference deviates more and more from π rad as the wavelength moves away from 510 nm. It is the increasing reflection at the ends of the visible spectrum (λ≈400 nm and λ≈700 nm), where Δϕ deviates significantly from π rad, that gives a reddish-purple tinge to the lenses on cameras and binoculars. Homework problems will let you explore situations where only one of the two reflections has a reflection phase shift of π rad.